Why Two Metals Are Better Than One for Heterodinuclear Cobalt–Zirconium-Catalyzed Kumada Coupling
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چکیده
منابع مشابه
Two metals are better than one in the gold catalyzed oxidative heteroarylation of alkenes.
We present a detailed study of the mechanism for oxidative heteroarylation, based on DFT calculations and experimental observations. We propose binuclear Au(II)-Au(II) complexes to be key intermediates in the mechanism for gold catalyzed oxidative heteroarylation. The reaction is thought to proceed via a gold redox cycle involving initial oxidation of Au(I) to binuclear Au(II)-Au(II) complexes ...
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ژورنال
عنوان ژورنال: Organometallics
سال: 2018
ISSN: 0276-7333,1520-6041
DOI: 10.1021/acs.organomet.8b00449